On the Reaction between Ammonia and Silicon Tetrachloride : Crystal-Model Study of the Products of the Reaction between Ammonia and Silicon Tetrachloride
The reaction products between ammonia and silicon tetrachloride were studied at room temperature. 1) By the X-ray analysis of the powder method and the microphoto-analysis, we found that one of the two reaction products is ammonium chloride, another diimino monosilan, and the reaction formula of this reaction at room temperature, as SiCl_4+6NH_3=4NH_4Cl+Si(NH)_2 2) The crystal from of silicon of diimino monosilan belongs to hexagonal system and the lattice constant is a=6, 6_6K.X. and c/a=1.0, On the crystal group it needs to be confirmed. As the experimental method we applied for the determination of the crystal form was expanded by BUERGER recently, so we are wishing to confirm our crystals by his simmetry theorem.
雑誌名
お茶の水女子大學自然科學報告
巻
1
ページ
57 - 63
発行年
1951-03
ISSN
00298190
書誌レコードID
AN00033958
フォーマット
application/pdf
形態
433509 bytes
日本十進分類法
400
出版者
お茶の水女子大学
資源タイプ
紀要論文
資源タイプ・ローカル
紀要論文
資源タイプ・NII
Departmental Bulletin Paper
資源タイプ・DCMI
text
資源タイプ・ローカル表示コード
03
所属
Department of Chemistry, Faculty of Science, Ochanomizu University
Tokyo Institute of Technology
四塩化珪素とアンモニアとの反應に就いて
KJ00004829252.pdf
(433.51KB)
