{"created":"2021-03-01T06:40:10.756655+00:00","id":34842,"links":{},"metadata":{"_buckets":{"deposit":"323e418c-b8d7-472d-8e78-698ac3faa9ac"},"_deposit":{"id":"34842","owners":[],"pid":{"revision_id":0,"type":"depid","value":"34842"},"status":"published"},"_oai":{"id":"oai:teapot.lib.ocha.ac.jp:00034842","sets":["347:359:629"]},"item_11_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1977-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"70","bibliographicPageStart":"67","bibliographicVolumeNumber":"28","bibliographic_titles":[{"bibliographic_title":"お茶の水女子大學自然科學報告"}]}]},"item_11_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_11_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"紀要論文","subitem_description_type":"Other"}]},"item_11_description_7":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A number of studies have been carried out on the Raman spectra of metallic hydroxo complexes. However, it seems that there are no published data on the Raman spectra of the hydroxo complexes of tin (II) and lead (II) formed in very concentrated alkali solutions. Such ions (the so-called stannite and plumbite ions) were described formerly as [MO_2]^<2->, and more recently as [M(OH)_4]^<2->, but recent literature tends to formulate them as [HMO_2]^- or [M(OH)_3]^-. The last formulation seems to be the most reasonable, in view of a number of stability and solubility data. It is also in conformity with the structural expectation, that the inert electron pair (ns^2) of Sn^<2+> or Pb^<2+> will tend to occupy a coordination site and favor the formation of the pyramidal (i.e. NH_3-like) [M(OH)_3]^- complex in strongly alkaline solutions. We have tried to observe the Raman spectra of such complexes, and, for the sake of comparison, also those of antimony (III) fluoride, which is isoelectronic with [Sn(OH)_3]^-, in aqueous and organic solutions,","subitem_description_type":"Other"}]},"item_11_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"70114","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ソネ, コウゾウ"}]},{"nameIdentifiers":[{"nameIdentifier":"70115","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ハギワラ, マリ"}]}]},"item_11_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"お茶の水女子大学"}]},"item_11_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00033958","subitem_source_identifier_type":"NCID"}]},"item_11_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00298190","subitem_source_identifier_type":"ISSN"}]},"item_11_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"400","subitem_subject_scheme":"NDC"}]},"item_11_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"220711 bytes"}]},"item_11_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_11_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_11_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_11_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"03"}]},"item_11_text_79":{"attribute_name":"所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Faculty of Science, Ochanomizu University"},{"subitem_text_value":"Department of Chemistry, Faculty of Science, Ochanomizu University"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sone, Kozo"}],"nameIdentifiers":[{"nameIdentifier":"70112","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hagiwara, Mari"}],"nameIdentifiers":[{"nameIdentifier":"70113","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-04-19"}],"displaytype":"detail","filename":"KJ00004829906.pdf","filesize":[{"value":"220.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00004829906.pdf","url":"https://teapot.lib.ocha.ac.jp/record/34842/files/KJ00004829906.pdf"},"version_id":"f1f5e924-6bf5-4ea1-b514-44b0132e6ba0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Raman Spectra of Hydroxo Complexes of Tin (II) and Lead (II) in Strongly Alkaline Solutions, and of Antimony (III) Fluoride in Various Solvents","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Raman Spectra of Hydroxo Complexes of Tin (II) and Lead (II) in Strongly Alkaline Solutions, and of Antimony (III) Fluoride in Various Solvents"}]},"item_type_id":"11","owner":"1","path":["629"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-04-30"},"publish_date":"2008-04-30","publish_status":"0","recid":"34842","relation_version_is_last":true,"title":["Raman Spectra of Hydroxo Complexes of Tin (II) and Lead (II) in Strongly Alkaline Solutions, and of Antimony (III) Fluoride in Various Solvents"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-12T05:39:26.623714+00:00"}