{"created":"2021-03-01T06:40:14.307680+00:00","id":34893,"links":{},"metadata":{"_buckets":{"deposit":"2a314776-073e-410b-837c-d4c3ac8a9b7a"},"_deposit":{"id":"34893","owners":[],"pid":{"revision_id":0,"type":"depid","value":"34893"},"status":"published"},"_oai":{"id":"oai:teapot.lib.ocha.ac.jp:00034893","sets":["347:359:620"]},"item_11_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1973-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"25","bibliographicPageStart":"13","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"お茶の水女子大學自然科學報告"}]}]},"item_11_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_11_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"紀要論文","subitem_description_type":"Other"}]},"item_11_description_7":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Several nickel chelates with trans-1, 2-diaminocyclohexane (=cyclohexanediamine ; abbreviated as chxn), Ni chxn_2X_2・nH_2O (X=Cl, Br, NO_3 or ClO_4 ; n=0 or 2) and Ni chxn_3X_2・nH_2O (X=Cl, Br or NO_3 ; n=1 or 2.5) were prepared, together with some copper (II) chelates with the same ligand, Cu chxn_2(NO_3)_2 and Cu chxn L (NO_3)_2・nH_2O (L=2, 2'-bipyridine : bip or 1, 10-phenanthroline : phen ; n=0 or 1). Two types of the bis-chxn nickel complexes are obtained, one is yellow diamagnetic and square planar [Ni chxn_2]X_2 and the other, purple, paramagnetic and octahedral [Ni chxn_2(H_2O)_2]X_2. These two chelates are in equilibrium in the aqueous solution.","subitem_description_type":"Other"}]},"item_11_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"69953","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ツチダ, マサコ"}]}]},"item_11_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"お茶の水女子大学"}]},"item_11_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00033958","subitem_source_identifier_type":"NCID"}]},"item_11_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00298190","subitem_source_identifier_type":"ISSN"}]},"item_11_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"400","subitem_subject_scheme":"NDC"}]},"item_11_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"749022 bytes"}]},"item_11_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_11_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_11_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_11_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"03"}]},"item_11_text_79":{"attribute_name":"所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Faculty of Science, Ochanomizu University(Present office):Department of Chemistry, Faculty of Science, Tokyo Institute of Technology"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tsuchida, Masako"}],"nameIdentifiers":[{"nameIdentifier":"69952","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-04-19"}],"displaytype":"detail","filename":"KJ00004829778.pdf","filesize":[{"value":"749.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00004829778.pdf","url":"https://teapot.lib.ocha.ac.jp/record/34893/files/KJ00004829778.pdf"},"version_id":"bb3d57b0-54fe-4251-9833-85122328273f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Chelate Complexes of Nickel (II) and Copper (II) with trans-1, 2-Diaminocyclohexane","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Chelate Complexes of Nickel (II) and Copper (II) with trans-1, 2-Diaminocyclohexane"}]},"item_type_id":"11","owner":"1","path":["620"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-04-30"},"publish_date":"2008-04-30","publish_status":"0","recid":"34893","relation_version_is_last":true,"title":["Chelate Complexes of Nickel (II) and Copper (II) with trans-1, 2-Diaminocyclohexane"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-12T05:39:31.806027+00:00"}