{"created":"2021-03-01T06:40:23.438519+00:00","id":35026,"links":{},"metadata":{"_buckets":{"deposit":"97d01542-f61f-4ceb-b710-3a57d4489f65"},"_deposit":{"id":"35026","owners":[],"pid":{"revision_id":0,"type":"depid","value":"35026"},"status":"published"},"_oai":{"id":"oai:teapot.lib.ocha.ac.jp:00035026","sets":["347:359:590"]},"item_11_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1958-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"46","bibliographicPageStart":"24","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"お茶の水女子大學自然科學報告"}]}]},"item_11_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_11_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"紀要論文","subitem_description_type":"Other"}]},"item_11_description_7":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"樹脂加工を施した木綿布は,一般に汚れにくく付いた汚れも洗浄しやすいと称されているが,その実態については疑念をもつて来たので,前報までに準じた人工汚染の方法により汚染性を比較し,次にそれらの洗浄試験を行つて洗浄性を検討した。得られた諸結果のなかで主要なものを次に列挙する。本報告には,直接,汚染に関連した実験結果だけを述べたが,これらの原因についてはさらに検討を要する点も多く,引続き実験中であり,別の機会に報告を行う。1)市販状態の加工布は,四塩化炭素分散の人工汚染(S_1)によつては,それらの未加工布とほぼ同程度の汚染性を示すが,水分散の人工汚染(S_2)によると未加工布よりもずつと汚染されやすくなる。この一因として,浸漬による水性汚染の場合には分散剤や撥水剤の併用が却つて汚染性を高めるものと認められる。2)市販状態の加工布を汚染したものは,いずれの汚染方法によつた場合にも,それらの未加工布に比べ,蒸溜水洗浄による洗浄性が著しく低下する。四塩化炭素分散標準汚染液型(S_3)に水分散汚染液(S_2)におけると同量の非イオン活性剤を添加して人工汚染に使用したもの(S_1)でも,この傾向は全く同様である。3)木綿布の樹脂加工剤として普通に用いられている各種の樹脂原液を,それぞれ単独に同量あて使用して樹脂加工を施した試料によると,次のことが認められた。i)アクリル系樹脂による加工布は未加工布に比べ,S_1,S_2どちらの汚染方法による場合にも汚染性が大きく,なお,付着した汚れは,水洗浄(W_1)ではもちろん石けん水洗浄(W_2)によつても著しく洗浄し難い。ii)参考として同じく単独で用いた撥水剤だけによる加工布は,汚染性についてはアクリル系と同様の傾向を示すが,汚れは石けん水洗浄によつては未加工布程度に落ちる。ただし,この場合にもS_2汚染により水洗浄を行つた際の洗浄率はかなり低い。iii)その他の,尿素・メラミンおよびそれらの誘導体を主成分とする樹脂加工布は,汚染性は未加工布よりもやや高いか同程度であり,水洗浄率は未加工布よりもやや低下し,石けん水洗浄率は未加工布とほぼ同程度であるが,樹脂型相互間における差異はあまり顕著ではなく,エチレン尿素系によるもの(R_4)が僅かに高い数値を示している。","subitem_description_type":"Other"},{"subitem_description":"4)前項の場合,いずれもS_1汚染のほうがS_2汚染よりも汚染性が大きく,従つて市販加工布において汚染率がS_1<S_2であることは,浸透剤その他の配合成分による影響と考えられる。石けん水による洗浄のほうが,いずれも水だけによる洗浄率よりは高い。付着樹脂量と汚染に関する性質との関連性は明らかではないが,同一樹脂の場合における加工布の防皺性との関係をみると,防皺性の高い(従つて付着量も多いと考えられる)状態のものは,概して洗浄性とくに水洗浄率が低下する傾向を示す。5)最も普通に用いられているメチロールエチレン尿素系(R_4)による樹脂加工条件と,加工布の汚染性・洗浄性との間には,次のような諸点が認められた。i)触媒の量を増加しても,少くとも加工布の汚染・洗浄に関しては影響がほとんどない。ii)キュアリングの時間を長くしても,汚染性にはほとんど変化がないが,汚れの水洗浄率(とくにS_1汚染の場合)はかなり低下する。しかし,反面に石けん水洗浄率は次第に上昇を示し,未加工布よりも高くなる。iii)ソーピングの有無は汚染性については最も大きな要素となり,S_1,S_2いずれの汚染方法による場合にも,ソーピングを施すことにより汚染性が高まる。しかしながら,汚れの洗浄率はソーピングを施した場合のほうが高く(とくにS_1汚染の場合),繊維表面に付着状態の不要定な樹脂成分が汚染に関与する効果が大きい。ただし,キュアリングが進みすぎるとこのようなソーピングの効果も薄れてゆく。","subitem_description_type":"Other"},{"subitem_description":"Resin finished fabrics are usually considered that difficult to be soiled and easy to be de-soiled. However we have some question about this conception, both from the results of several preparatory experimentals and from the experiences in end uses. The structure of using resins and the condition of application to fabrics are seemed big factors in the soiling behaviour. In this paper, the soiling characteristics of resin finished cotton fabrics, so-called the crease resistant fabrics, are compared using the artificial soiling medium, that is the dispersion of carbonblack and others in carbontetrachloride (S_1) or in water (S_2). Soil preventive properties in a wide sense, see the previous papers, are also discussed as the detersive characteristics by the method of washing test. The soiled fabrics for this test are prepared using the same resin finished fabrics as those for soiling test. The chief results obtained are as follows. 1) Commercial resin finished fabrics are more easily soiled by the water-medium soiling (S_2) than the unfinished original fabrics (R_0), and moreover the soils on the former fabrics are mo\\\nre difficult to be deterged, when washed in water (W_1), than those on the latter fabrics. 2) The difference of the dispersing medium in the artificial soiling bath, CCI_4(S_1) or water (S_2), is a not so essential factor in the soiling and deterging characteristics of commerical resin finished fabrics. 3) Among the several types of resin which are commonly used for finishing, the following characteristics are found. Fabrics finished by polyacrylic ester or its copolymer (R_5, R_6) have special easiness to be soiled, and the soils on those are particularly difficult to be deterged, even if washed in 0.3% soap solution (W_2). Urea, melamine and their methylol derivatives (R_1〜R_4), when used as finishing agent, have almost the same effect on the soiling property of fabrics, but on the detergency of finished fabrics show differences in some extent. However the soils on those fabrics are more difficult to be removed when washed in water (W_1) than those on unfinished one (R_0), but have almost the same detergency when washed in soap solution (W_2). Fabrics finished by water repellent agent (R_7) have almost the same quality of the soiling characteristics as those finished by acrylic polymer, but their detergency in soap solution (W\\\n_2) are higher than F_0, although that in water (W_1) are rather lower than F_0. 4) Degrees of soiling of these resin finished fabrics are higher by CCI_4-medium (S_1) than H_2O-medium (S_2), and the detergency of soil on those fabrics are higher by washing in soap solution (W_2) than in water (W_1). Finished fabrics showing high crease resistance, which assumed having much resin pick-up, have low detergency, especially when washed in water. 5) Amount of the catalyst (accelerator) has little effect on the soiling and deterging characteristics of the finished fabrics. The curing (baking) time has also little effect on the soiling property, but the longer the curing time, the lower the detergency in water (W_1), although the detergency in soap solution (W_2) increases with the time of curing. The effect of the soaping after the curing is a big factor in soiling characteristics, and the soaped fabrics (P_2) show higher degrees both of soiling and of detergency than the unsoaped fabrics (P_1).","subitem_description_type":"Other"}]},"item_11_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"69463","nameIdentifierScheme":"WEKO"}],"names":[{"name":"マツカワ, テツヤ"}]},{"nameIdentifiers":[{"nameIdentifier":"69464","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ワタナベ, マサコ"}]}]},"item_11_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"お茶の水女子大学"}]},"item_11_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00033958","subitem_source_identifier_type":"NCID"}]},"item_11_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00298190","subitem_source_identifier_type":"ISSN"}]},"item_11_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"400","subitem_subject_scheme":"NDC"}]},"item_11_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"1482751 bytes"}]},"item_11_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"紀要論文"}]},"item_11_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Departmental Bulletin Paper"}]},"item_11_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_11_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"03"}]},"item_11_text_79":{"attribute_name":"所属","attribute_value_mlt":[{"subitem_text_value":"Laboratory of Textiles, Faculty of Home Economics, Ochanomizu University"},{"subitem_text_value":"Laboratory of Textiles, Faculty of Home Economics, Ochanomizu University"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松川, 哲哉"}],"nameIdentifiers":[{"nameIdentifier":"69461","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"渡邊, 正子"}],"nameIdentifiers":[{"nameIdentifier":"69462","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsukawa, Tetsuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69465","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Masako","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69466","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-04-19"}],"displaytype":"detail","filename":"KJ00004829473.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00004829473.pdf","url":"https://teapot.lib.ocha.ac.jp/record/35026/files/KJ00004829473.pdf"},"version_id":"1861e8f2-23aa-4cf3-a486-afac90c72439"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"繊維製品の汚れに関する研究(第5報) : 樹脂加工綿布の汚染性および洗浄性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"繊維製品の汚れに関する研究(第5報) : 樹脂加工綿布の汚染性および洗浄性"},{"subitem_title":"Studies on the Soiling of Fabrics Part 5 : The Soiling and Deterging Characteristics of Resin Finished Cotton Fabrics","subitem_title_language":"en"}]},"item_type_id":"11","owner":"1","path":["590"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-04-30"},"publish_date":"2008-04-30","publish_status":"0","recid":"35026","relation_version_is_last":true,"title":["繊維製品の汚れに関する研究(第5報) : 樹脂加工綿布の汚染性および洗浄性"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-12T06:09:18.717853+00:00"}