{"created":"2021-03-01T06:06:46.967504+00:00","id":4950,"links":{},"metadata":{"_buckets":{"deposit":"440c2976-7a67-4e42-bdca-1880cbeb96f0"},"_deposit":{"id":"4950","owners":[],"pid":{"revision_id":0,"type":"depid","value":"4950"},"status":"published"},"_oai":{"id":"oai:teapot.lib.ocha.ac.jp:00004950","sets":["226:216:221"]},"control_number":"4950","item_12_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999-09-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1999","bibliographicPageEnd":"59","bibliographicPageStart":"58","bibliographic_titles":[{"bibliographic_title":"日本液晶学会討論会講演予稿集"}]}]},"item_12_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_12_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"学術雑誌論文","subitem_description_type":"Other"}]},"item_12_description_6":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Crystal structures of 4-cyano-4'-alkylbiphenyls (nCB) and 4-cyano-4'-alkoxylbiphenyls (nOCB) show a different tendency: a remarkable even-odd effect for the former and dominant CN-CN interaction for the latter. In order to elucidate the difference between the two series, FT-IR spectra have been measured. CN stretching vibration frequencies for dilute solutions of CCl_4 (0.01 mol/l) are 0.5 cm^<-1> higher for nCB than for nOCB, giving a direct evidence of the different intramolecular interaction for isolated moleculeS. In mesophases, the frequencies on average are 1.0 cm^<-1> higher for nCB than for nOCB. Thus, the difference in mesophases (1.0 cm^<-1>) is larger than that for isolated molecules (0.5 cm^<-1>). Similar results were obtained for 4-cyanophenyl 4-alkoxybenzoates and 4-alkoxyphenyl 4-cyanobenzoates, showing the difference of intra- and intermolecular interactions due to the reversed directions of ester linkages with respect to the CN groups.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_12_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本液晶学会"}]},"item_12_relation_54":{"attribute_name":"異版である","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://ci.nii.ac.jp/naid/110001464294/","subitem_relation_type_select":"URI"}}]},"item_12_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"日本液晶学会"},{"subitem_rights":"本文データは学協会の許諾に基づきCiNiiから複製したものである"}]},"item_12_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_12_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11639022","subitem_source_identifier_type":"NCID"}]},"item_12_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"420","subitem_subject_scheme":"NDC"}]},"item_12_subject_24":{"attribute_name":"NIIサブジェクト","attribute_value_mlt":[{"subitem_subject":"物理学","subitem_subject_scheme":"Other"}]},"item_12_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"289597 bytes"}]},"item_12_text_47":{"attribute_name":"資源タイプ・ローカル","attribute_value_mlt":[{"subitem_text_value":"学術雑誌論文"}]},"item_12_text_48":{"attribute_name":"資源タイプ・NII","attribute_value_mlt":[{"subitem_text_value":"Journal Article"}]},"item_12_text_49":{"attribute_name":"資源タイプ・DCMI","attribute_value_mlt":[{"subitem_text_value":"text"}]},"item_12_text_50":{"attribute_name":"資源タイプ・ローカル表示コード","attribute_value_mlt":[{"subitem_text_value":"01"}]},"item_12_text_79":{"attribute_name":"所属","attribute_value_mlt":[{"subitem_text_value":"お茶大・院人間文化"},{"subitem_text_value":"お茶大・院人間文化"},{"subitem_text_value":"お茶大・院人間文化"}]},"item_1622774516477":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"飯室, 瑞枝"}],"nameIdentifiers":[{"nameIdentifier":"106686","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"栗林, 美樹"}],"nameIdentifiers":[{"nameIdentifier":"106687","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"堀, 佳也子"}],"nameIdentifiers":[{"nameIdentifier":"106688","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"IIMURO, Mizue","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"106689","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"KURIBAYASHI, Miki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"106690","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"HORI, Kayako","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"106691","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-04-26"}],"displaytype":"detail","filename":"日本液晶学会討論会講演予稿集1999_飯室栗林堀.pdf","filesize":[{"value":"289.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"日本液晶学会討論会講演予稿集1999_飯室栗林堀.pdf","url":"https://teapot.lib.ocha.ac.jp/record/4950/files/日本液晶学会討論会講演予稿集1999_飯室栗林堀.pdf"},"version_id":"9a0c6823-9776-42f9-bdbe-7fede6ac2d41"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"1C07 シアノ基をもつ液晶性物質の分子内および分子間相互作用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"1C07 シアノ基をもつ液晶性物質の分子内および分子間相互作用","subitem_title_language":"ja"},{"subitem_title":"Intra-and intermolecular interaction in mesogenic cyano compounds","subitem_title_language":"en"}]},"item_type_id":"12","owner":"17","path":["221"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-06-12"},"publish_date":"2008-06-12","publish_status":"0","recid":"4950","relation_version_is_last":true,"title":["1C07 シアノ基をもつ液晶性物質の分子内および分子間相互作用"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2022-12-12T06:02:58.014062+00:00"}