{"created":"2021-03-01T06:06:47.101435+00:00","id":4952,"links":{},"metadata":{"_buckets":{"deposit":"cc561835-0962-4af4-a7a2-f1cb96f46a04"},"_deposit":{"id":"4952","owners":[],"pid":{"revision_id":0,"type":"depid","value":"4952"},"status":"published"},"_oai":{"id":"oai:teapot.lib.ocha.ac.jp:00004952","sets":["226:216:221"]},"item_12_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1998-10-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1998","bibliographicPageEnd":"301","bibliographicPageStart":"300","bibliographic_titles":[{"bibliographic_title":"日本液晶学会討論会講演予稿集"}]}]},"item_12_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_12_description_46":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"学術雑誌論文","subitem_description_type":"Other"}]},"item_12_description_6":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have synthesized a homologous series of 4-(4-alkoxyphenoxycarbonyl)phenyl 4-trifluoromethylbenzoates (compounds 1) and examined their thermal properties and molecular arrangements. The transition temperatures, the latent heats and the characterizations of the mesophases were achieved by polarizing microscope, DSC, and small angle X-ray diffraction measurements. These homologous series of 1 show nematic, smectic A and/or highly ordered smectic phases. The layer spacings of the smectic A phases indicate that the each layer spacing of the homologs is about 2 Å longer than the molecular length. These results indicate that the trifluoromethyl group is located at the boundary of the smectic walls.","subitem_description_type":"Abstract"}]},"item_12_publisher_36":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本液晶学会"}]},"item_12_relation_54":{"attribute_name":"異版である","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"http://ci.nii.ac.jp/naid/110001464162/","subitem_relation_type_select":"URI"}}]},"item_12_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"日本液晶学会"},{"subitem_rights":"本文データは学協会の許諾に基づきCiNiiから複製したものである"}]},"item_12_select_19":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_12_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11639022","subitem_source_identifier_type":"NCID"}]},"item_12_subject_20":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"420","subitem_subject_scheme":"NDC"}]},"item_12_subject_24":{"attribute_name":"NIIサブジェクト","attribute_value_mlt":[{"subitem_subject":"物理学","subitem_subject_scheme":"Other"}]},"item_12_text_18":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_text_value":"316720 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液晶核末端にトリフルオロメチル基を持つ液晶の合成と分子配列","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"2B10 液晶核末端にトリフルオロメチル基を持つ液晶の合成と分子配列","subitem_title_language":"ja"},{"subitem_title":"Synthesis and Molecular Arrangement of Liquid Crystals having a Trifluoromethyl Group at the Terminal Position","subitem_title_language":"en"}]},"item_type_id":"12","owner":"1","path":["221"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-06-13"},"publish_date":"2008-06-13","publish_status":"0","recid":"4952","relation_version_is_last":true,"title":["2B10 液晶核末端にトリフルオロメチル基を持つ液晶の合成と分子配列"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-12T06:01:29.336857+00:00"}